(PDF) Gypsum solubility in water at 25°C
The analysis of published data and our experimental results showed that the existing estimates of gypsum solubility in water (Cm↑) at 25°C range from 0.0147 to 0.0182 M.
WhatsApp: +86 18221755073The analysis of published data and our experimental results showed that the existing estimates of gypsum solubility in water (Cm↑) at 25°C range from 0.0147 to 0.0182 M.
WhatsApp: +86 18221755073Solubility data of gypsum in water as accepted by Krumgalz (2018),h i s fi t (red line), our fi t (black line) with reduced data set (see Table 3). TABLE 3 Deleted data from the gypsum data set ...
WhatsApp: +86 18221755073Also, the gypsum form affects the solubility in water which may influence the concentration of sulfate ions in solution during cement hydration [57], [58], [59]. Under 40 °C, the dihydrate gypsum has the lowest solubility, followed by the anhydrite and the hemihydrate [60].
WhatsApp: +86 18221755073It is a by-product of the waste materials generated during the synthesis of phosphoric acid. Preventing numerous damages induced by the precipitation of gypsum requires a deep understanding of predicting its solubility under various thermodynamic conditions [16,18].
WhatsApp: +86 18221755073The solubility of gypsum at 20°C is 2.531 g/L or 14 mM/L, which is roughly 140 times lower than the solubility of common salt, but two orders of magnitude greater than the solubility of CaCO3 in ...
WhatsApp: +86 18221755073As the waste of coal-fired power plant, desulphurization gypsum is mainly composed of CaSO 3 and CaSO 4, which can replace Na+ in saline-alkali soil to improve saline-alkali soil.
WhatsApp: +86 18221755073Gypsum solubility (at 25 °C) and logarithm of rate coefficients for gypsum growth at a range of temperatures (25 °C, 50 °C, 70 °C, and 90 °C) in stoichiometric solutions as a function of ...
WhatsApp: +86 18221755073The databases of alkaline and alkaline earth sulfate solubilities in water at various temperatures were created using experimental data from the publications over about the last two centuries.
WhatsApp: +86 18221755073This study attempted to characterize the P release behavior of the saline–sodic soil amended with gypsum alone (G25 and G50: 25 and 50% gypsum requirement:) or with farmyard manure (G25FYM) and city waste compost from Karnal (G25CK) and Delhi (G25CD). ... under alkaline compared to salinity. Saline/alkaline stress was the primary driver of ...
WhatsApp: +86 18221755073Phospho-gypsum is mainly composed of CaSO 4 ·2H 2 O, and other complex impurities such as soluble phosphorus, soluble fluorine, organics, or alkali metal salts. ... In this study, the influence of soluble phosphorus on the hydration process and the mechanism of calcined gypsum under deep retarding condition were studied. The data showed that ...
WhatsApp: +86 18221755073Effect of sodium hydroxide under various conditions | A quantitative estimation of the effect of sodium hydroxide on the solubility of gypsum in the presence of lime at 30, 60 and 100°C is given.
WhatsApp: +86 18221755073Although the reduction of water soluble Na + was not significant in HF soil under all amendments, there was a modest decrease in water soluble Na + (by 43 mg kg −1) under CaSO 4 treatment. Clearly, water soluble Ca 2+ showed a significant increase under application of CaSO 4 (by 1156–3018 mg kg −1 ) and biochar (by 791–1138 mg kg −1 ...
WhatsApp: +86 18221755073In addition, the formation of a sparingly soluble CaCO3 coating around the gypsum particles after mixing in a highly alkaline seawater/supernatant liquor (SNL) solution greatly reduced the rate of ...
WhatsApp: +86 18221755073Saline–alkali soils have high sodicity, high pH, and high levels of soluble salts, as well as carbonates. This study aimed to evaluate the effect of cattle manure and chicken manure combined with gypsum at three levels on reclaiming a saline–alkali soil, through a soil column experiment. Combined treatments were more effective than those of sole gypsum in reducing …
WhatsApp: +86 18221755073The analysis of published data and our experimental results showed that the existing estimates of gypsum solubility in water (C m ↑) at 25°C range from 0.0147 to 0.0182 M. Such a scatter (more than 20%) is the result of a combined influence of experimental conditions and ability of gypsum to form supersaturated solutions. This influence appears most noticeable …
WhatsApp: +86 18221755073In the gypsum karst areas the pH value of the water is slightly alkaline (pH 7.2). The geological background sulphate does not show any toxic effects on environment. The dissolving of …
WhatsApp: +86 18221755073where r ij and σ ij are the actual and reference distances between atoms i and j, respectively; ε o is the permittivity of free space (ε o = 8.8543 × 10 –12 C 2 J –1 m –1); ε ij is the potential well-depth; and q i and q j are the value of the charge on atoms i and j.The LJ interactions between unlike atoms are treated with the sixth-order mixing rule. 20 The atom-based summation ...
WhatsApp: +86 18221755073Alkali metals can increase the content of sulfate ions in the early solution by forming the better soluble alkali sulfates in the clinker and by promoting gypsum dissolution (within the range of alkali content added in this study), which may be one of the reasons for the elevated water-soluble hexavalent chromium content.
WhatsApp: +86 18221755073The results of this study indicate that gypsum solubility could be estimated by employing the CMIS approach with high accuracy in Na-Ca-Mg-Fe-Al-H-Cl-H2O system over …
WhatsApp: +86 18221755073It was found the sulfate precipitation completed in 15 mins with stirring under an alkaline condition (pH ≈ 12) and was not affected by temperature (15°C to 45°C).
WhatsApp: +86 18221755073This was primarily attributed to the precipitation of soluble alkali compounds (e.g. NaOH, Na2CO3, NaHCO3, NaAl(OH)4, KOH, K2CO3)[34] to more stable calcite, tri-calcium aluminate, hydrocalumite, and other calcium aluminate minerals during the treatment with gypsum [33,35–38], which exhibit lower solubility and therefore give lower alkaline ...
WhatsApp: +86 18221755073A Walnut Gulch rainfall simulator was used to determine runoff water quality and salt balance of a Sandy Loam moderately saline-alkaline site containing 0.27% of gypsum near Moab, Utah.
WhatsApp: +86 18221755073The calcium ion in the gypsum replaces the sodium salt from the soil exchange sites and helps to bring the salt into solution. Numerous studies have examined the reclamation of alkaline sodic and ...
WhatsApp: +86 18221755073Gypsum is calcium sulfate (CaSO 4).Refined gypsum in the anhydrite form (no water) is 29.4 percent calcium (Ca) and 23.5 percent sulfur (S). Usually, gypsum has water associated in the molecular structure (CaSO 4 ·2H2O) and is approximately 23.3 percent Ca and 18.5 percent S (plaster of paris). Gypsum fertilizer usually has other impurities so grades are approximately 22 …
WhatsApp: +86 18221755073Solubility Measurements and Predictions of Gypsum, Anhydrite, and Calcite Over Wide Ranges of Temperature, Pressure, and Ionic Strength with Mixed Electrolytes. Rock …
WhatsApp: +86 18221755073Gypsum can exist stably in the bauxite residue, but its lower solubility will cause a low Ca content [17]. As a result, the efficiency of gypsum to neutralize the alkalinity of bauxite residue is limited. Solubilization of gypsum by complexation is …
WhatsApp: +86 18221755073Gypsum has been used for centuries to reclaim sodium affected soils (alkali soils). It is effective since it has good solubility regardless of soil pH. In fact, its solubility is enhanced in sodic soils. Some data would suggest that the …
WhatsApp: +86 18221755073According to experimental data (25°C), the solubility of gypsum particles in water is inversely proportional to their size at r < 1 μm and is r-invariant for larger grains. The invariance of (C …
WhatsApp: +86 18221755073As Jones et al. (2015) reported, Ca 2 + could react with soluble alkaline anions such as CO 3 2 −, HCO 3 −, OH − and Al(OH) 4 −. The mechanisms of both gypsum and phosphogypsum were similar, as both materials can provide excess calcium to precipitate soluble alkali (Kopittke et al., 2005, Jones et al., 2012). Notably, phosphogypsum ...
WhatsApp: +86 18221755073DOI: 10.1016/0098-3004(93)90039-8 Corpus ID: 129772192; Prediction of halite, gypsum, and anhydrite solubility in natural brines under subsurface conditions @article{He1993PredictionOH, title={Prediction of halite, gypsum, and anhydrite solubility in natural brines under subsurface conditions}, author={Shiliang He and John W. Morse}, journal={Computers & Geosciences}, …
WhatsApp: +86 18221755073The solubilities and dissolution rates of three gypsum sources (analytical grade (AG), phosphogypsum (PG) and mined gypsum (MG)) with six MG size fractions ((mm) > 2.0, 1.0-2.0, 0.5-1.0, 0.25-0.5, 0.125-0.25, and PG > MG) due to reactivity and surface area differences, with 1:20 gypsum:solution suspensions reaching saturation within 15 s (AR) to 30 min (MG > …
WhatsApp: +86 18221755073According to experimental data (25°C), the solubility of gypsum particles in water is inversely proportional to their size at r < 1 μm and is r-invariant for larger grains. The invariance …
WhatsApp: +86 18221755073As an industrial by-product of flue gas desulfurization, flue gas desulfurization gypsum (FGD gypsum), whose main component is CaSO 4 · 2H 2 O, is an ideal raw material for mineralization. The technical problem of indirect mineralization lies in the efficient recycling of leaching agents, while amino acids have the lowest solubility at their isoelectric point, and thus …
WhatsApp: +86 18221755073Gypsum is slightly water soluble under normal conditions and exhibits a retrograde solubility becoming less soluble at temperatures higher than 42 ... While accumulations of pedogenic gypsum commonly occur in alkaline environments, gypsum has also been reported as an acid sulfate weathering product in mine spoils (Doolittle et al., ...
WhatsApp: +86 18221755073This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided ... alkaline (pH 7.7), and calcareous (calcium carbonate equiv- ... which reduced P solubility. ∙ Gypsum-amended and unamended soils had a
WhatsApp: +86 18221755073The solubility of gypsum in different salt solutions containing Ca, Mg, Na, Cl, and SO4 was determined experimentally at 298 [degrees] K. Sixteen subprograms were developed by using five...
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